›› 2021, Vol. 57 ›› Issue (1): 0-0.

• 过程控制技术 •    

碳四烃烷基化工业废酸再生反应过程及关键控制

李若岩   

  1. 中国石油兰州寰球工程公司
  • 收稿日期:2020-07-22 出版日期:2021-01-01 发布日期:2021-03-11
  • 通讯作者: 李若岩

Reaction and Critical Control in Waste Acid Regeneration of C4 Alkylation

  • Received:2020-07-22 Online:2021-01-01 Published:2021-03-11

摘要: 摘要:以浓度89~90w%工业废硫酸为原料,废酸喷入1000℃高温焚烧炉焚烧裂解为SO2、O2和 H2O酸性混合气,SO2进行氧化反应为SO3,总转化率达 99.9w%,SO3与H2O水合生成浓度≥98w%新硫酸。采用“湿法”工艺建成的1.6万吨/年废硫酸再生装置,在废酸进料量为1.881t/h,产出工业品新硫酸1.727t/h,废酸再生回收率91.81w%。在废酸再生反应过程,主要实施了废酸再生装置中焚烧炉压力及反应温度控制,以及反应器入口温度控制、冷凝器入口温度控制、导热盐系统温度控制技术,通过这些关键的自动化控制及联锁保护技术的应用,实现了废酸再生装置的安全平稳运行。

关键词: 关键词:烷基化,废酸再生,湿法,焚烧,关键控制, Key Words: Alkylation, Waste acid regeneration, Wet process, Burn, Critical control

Abstract: Abstract: Under the condition of incineration at 1000 ℃,89~90w% waste sulfuric acid was injected into incinerator to burn and pyrolyse for the mixed acidic gas of SO2, O2 and H2O. The SO2 gas was converted to SO3 through oxidation, and the total conversion rate of SO3 was 99.9%. The regeneration recycling device of 16000 t/a waste acid was built using wet process. When the waste acid device was fed 1.881t/h, new sulfuric acid products were produced at 1.727t/h, the waste acid recovery rate was 91.81w%. During regeneration reaction of waste acid, it ensured the stable operation of waste acid device through critical controls and interlocks of pressure and temperature of waste acid regenerative incinerator, reactor inlet temperature, condenser inlet temperature, thermal salt system temperature and steam system pressure.